Your CD/DVD-R's ain't gonna last forever...
For maximum longevity, discs should be stored vertically and only be handled by the edges. Don't stick labels on them, and in the case of write-once CDs, don't write on them with anything but soft water-based or alcohol-based markers.
Rewriteable CDs and DVDs, as opposed to write-once discs, should not be used for long-term storage because they contain a heat-sensitive layer that decays much faster than the metal layers of other discs.
Full article here.